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Carbon Steel Desulfurization

Steelmaking involves two main stages: furnace oxidation followed by ladle (or secondary) refining. Slag plays a crucial role throughout this process, as it helps ensure clean, high-quality steel by protecting the molten metal, absorbing impurities, and supporting desulfurization. Removing sulphur is particularly important because its presence lowers steel quality. The effectiveness of desulfurization depends on the slag’s properties—such as its capacity, basicity, and viscosity—as well as the oxidation levels of both steel and slag, specific reaction conditions, and temperature. Sulphur is primarily eliminated through interactions between the slag and molten steel, with both rising slag droplets and the surface slag layer playing a part. Effective slag management not only reduces impurities but also protects refractory linings and enhances the overall quality of the finished steel.

Steel Slag Management

  • Slag forms a floating layer that’s removed during refining. It contains fluxes (like lime), deoxidation products, remnants from ores, and wear from lining.
  • Basicity, calculated as (CaO + MgO)/(SiO₂ + Al₂O₃), guides slag’s effectiveness for sulphur removal and lining protection.

Fluxing in Steel Making

  • Fluxes (like CaO, MgO, sometimes CaF₂) help make slag more effective at pulling sulphur out by lowering its melting point and viscosity.
  • A good slag is creamy and fluid—efficient for desulfurization and safe for the lining. Too hard or too fluid slags cause problems.

“Take care of your slag, the steel will take care of itself”—proper slag ensures better steel quality.

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All AF Chemicals products are carbon-free, saving energy, water, and emissions. By replacing natural fluorspar, we support circular economy, reduce mining impact, and lead the way toward a sustainable industrial future.

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Take care of your slag, the steel will take care of itself

Old proverb
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